Fluorid siřitý

Fluorid siřitý
	Strukturní vzorec
Obecné
Systematický název	fluorid siřitý
Sumární vzorec	SF3
Identifikace
Registrační číslo CAS	30937-38-3
SMILES	F[S](F)F
InChI	InChI=1S/F3S/c1-4(2)3
Vlastnosti
Molární hmotnost	89,064 g/mol
	Není-li uvedeno jinak, jsou použity; jednotky SI a STP (25 °C, 100 kPa). Některá data mohou pocházet z datové položky.

Fluorid siřitý (trifluorid síry) je radikálová anorganická sloučenina se vzorcem SF₃.^[1]^[2]

Struktura a příprava

Fluorid siřitý má pravděpodobně pyramidální strukturu.^[3]^[4]

SF₃ je možné získat z krystalů SF +
3 BF -
4 působením záření gama.^[1]

SF -
3

Sloučeninou iontu SF -
3 je například komplex Ir(Cl)(CO)(F)(SF₃)(Et₃P)₂, který lze připravit oxidační adicí fluoridu siřičitého na Ir(Cl)(CO)(PEt₃)₂ (Et = C₂H₅).^[5]^[6]

Odkazy

Reference

V tomto článku byl použit překlad textu z článku Sulfur trifluoride na anglické Wikipedii.

↑ ^a ^b J. R. Morton; K. F. Preston; S. J. Strach. The EPR spectrum of SF₃ Trapped in SF₃BF₄ Crystals. The Journal of Chemical Physics. 1978, s. 1392. DOI 10.1063/1.436766. Bibcode 1978JChPh..69.1392M.
↑ Jianming Deng; Chaoyang Wang; Qian-shu Li; Yaoming Xie; R. Bruce King; Henry F. Schaefer. Trifluorosulfane Ligand as an Analogue of the Nitrosyl Ligand: Highly Exothermic Fluorine Transfer Reactions from Sulfur to Metal in the Chemistry of SF₃ Metal Carbonyls of the First Row Transition Metals. Inorganic Chemistry. 2011, s. 2824–2835. DOI 10.1021/ic101994k. PMID 21366337.
↑ Karl K. Irikura. Structure and thermochemistry of sulfur fluorides SF_n (n = 1–5) and their ions SF +
n (n = 1–5). The Journal of Chemical Physics. 1995, s. 5357–5367. Dostupné online. DOI 10.1063/1.469263. Bibcode 1995JChPh.102.5357I.
↑ David E. Woon; Thom H. Dunning. Theory of Hypervalency: Recoupled Pair Bonding in SF_n (n = 1−6). The Journal of Physical Chemistry A. 2009, s. 7915–7926. DOI 10.1021/jp901949b. PMID 19499905. Bibcode 2009JPCA..113.7915W.
↑ Russell W. Cockman; E. A. V. Ebsworth; John H. Holloway. Complexes of iridium(III) containing the novel sulfur trifluoride ligand. Journal of the American Chemical Society. 1987, s. 2194–2195. DOI 10.1021/ja00241a055.
↑ Xiaozhen Gao; Nan Li; R. Bruce King. Formation of Difluorosulfane Complexes of the Third Row Transition Metals by Sulfur-to-Metal Fluorine Migration in Trifluorosulfane Metal Complexes: The Anomaly of Trifluorosulfane Iridium Tricarbonyl. Inorganic Chemistry. 2014, s. 12635-12642. DOI 10.1021/ic502375q. PMID 25397720.

Související články

[Morton-1] J. R. Morton; K. F. Preston; S. J. Strach. The EPR spectrum of SF₃ Trapped in SF₃BF₄ Crystals. The Journal of Chemical Physics. 1978, s. 1392. DOI 10.1063/1.436766. Bibcode 1978JChPh..69.1392M.

[2] Jianming Deng; Chaoyang Wang; Qian-shu Li; Yaoming Xie; R. Bruce King; Henry F. Schaefer. Trifluorosulfane Ligand as an Analogue of the Nitrosyl Ligand: Highly Exothermic Fluorine Transfer Reactions from Sulfur to Metal in the Chemistry of SF₃ Metal Carbonyls of the First Row Transition Metals. Inorganic Chemistry. 2011, s. 2824–2835. DOI 10.1021/ic101994k. PMID 21366337.

[3] Karl K. Irikura. Structure and thermochemistry of sulfur fluorides SF_n (n = 1–5) and their ions SF +
n (n = 1–5). The Journal of Chemical Physics. 1995, s. 5357–5367. Dostupné online. DOI 10.1063/1.469263. Bibcode 1995JChPh.102.5357I.

[4] David E. Woon; Thom H. Dunning. Theory of Hypervalency: Recoupled Pair Bonding in SF_n (n = 1−6). The Journal of Physical Chemistry A. 2009, s. 7915–7926. DOI 10.1021/jp901949b. PMID 19499905. Bibcode 2009JPCA..113.7915W.

[5] Russell W. Cockman; E. A. V. Ebsworth; John H. Holloway. Complexes of iridium(III) containing the novel sulfur trifluoride ligand. Journal of the American Chemical Society. 1987, s. 2194–2195. DOI 10.1021/ja00241a055.

[6] Xiaozhen Gao; Nan Li; R. Bruce King. Formation of Difluorosulfane Complexes of the Third Row Transition Metals by Sulfur-to-Metal Fluorine Migration in Trifluorosulfane Metal Complexes: The Anomaly of Trifluorosulfane Iridium Tricarbonyl. Inorganic Chemistry. 2014, s. 12635-12642. DOI 10.1021/ic502375q. PMID 25397720.

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